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How to completely purge everything then reinstall the desktop?
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Check out this link, see if there's something there that can help before you go the nuclear option.
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Also, before doing something drastic, rename the /home/USER/.config/xfce4 folder to something like xfce4.bak.
Then try to restart xfce again and see if it recreates that folder and its contents.
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if you run low on space(partition mostly full, for example) things sometimes misbehave.
Be Excellent to each other and Party On!
https://www.youtube.com/watch?v=rph_1DODXDU
https://en.wikipedia.org/wiki/Bill_%26_Ted%27s_Excellent_Adventure
Do unto others as you would have them do instantaneously back to you!
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