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greenjeans, as I understand it, that mess in the .desktop file only runs the first time you boot. After that, the correct background is set. Of course, that only counts if you install it. With the live iso, every time you boot it is the first boot.
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FTR, every time I've booted, including the time with Xfce before I added Mate, I get a blue Devuan wallpaper.
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